Synthesis of long aliphatic carbochain porphyrins and their LB films and study on their gas sensitivity

Yu Wen Liu, Yu E. Zhao, Li Bo Wang, Run Wei Wang, Hong Bin Liang, Hao Zhu, Xi Zhang Cao

Research output: Contribution to journalArticlepeer-review

Abstract

Tetranicotinamidephenyl porphyrin(TNAPP) reacts with n-C 16H 33Br and n-C 12H 25 Br, respectively to yield the products tetra (N-hexadecyl nicotinamide phenyl) porphyrin bromide(THNAPPBr) and tetra-(N-dodecylnicotinamide phenyl) porphyrin bromide. Its cobalt complex and zinc complex are also prepared. Those porphyrins and metal porphyrins have good film-forming properties. The gas sensitivity studies show that the six kinds of porphyrins are sensitive to NH 3 and has a fine selectivity.

Original languageEnglish (US)
Pages (from-to)x5-684
JournalKao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume18
Issue number5
StatePublished - 1997
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Chemistry

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