Substitutional studies on the anisotropic, semiconducting, molybdenum bronze, Li0.33MoO3

B. T. Collins; Kandalam Ramanujachary; M. Greenblatt; W. H. McCarroll; P. McNally; J. V. Waszczak

doi:10.1016/0022-4596(88)90225-3

Substitutional studies on the anisotropic, semiconducting, molybdenum bronze, Li_0.33MoO₃

B. T. Collins, Kandalam Ramanujachary, M. Greenblatt, W. H. McCarroll, P. McNally, J. V. Waszczak

Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Pure Li_0.33MoO₃ and vanadium-doped Li_0.33Mo_1-xV_xO₃ crystals were grown by a temperature gradient flux technique. Directional electrical resistivity measurements have been made on both the pure and doped crystals. The electrical properties of Li_0.33MoO₃ are highly anisotropic with resistivity values at room temperature of 1.8 × 10^-1 and 6.0 × 10² Ω cm along the c and b* directions, respectively. Li_0.33 MoO₃ shows complex semiconducting behavior and an anomalously low paramagnetic signal. The effects of vanadium substitution on the structure and transport properties of Li_0.33MoO₃ are dramatic. Attempts are made to correlate the observed electrical and magnetic behavior with the structure of Li_0.33MoO₃.

Original language	English (US)
Pages (from-to)	319-327
Number of pages	9
Journal	Journal of Solid State Chemistry
Volume	76
Issue number	2
DOIs	https://doi.org/10.1016/0022-4596(88)90225-3
State	Published - Jan 1 1988

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Substitutional studies on the anisotropic, semiconducting, molybdenum bronze, Li0.33MoO3",

abstract = "Pure Li0.33MoO3 and vanadium-doped Li0.33Mo1-xVxO3 crystals were grown by a temperature gradient flux technique. Directional electrical resistivity measurements have been made on both the pure and doped crystals. The electrical properties of Li0.33MoO3 are highly anisotropic with resistivity values at room temperature of 1.8 × 10-1 and 6.0 × 102 Ω cm along the c and b* directions, respectively. Li0.33 MoO3 shows complex semiconducting behavior and an anomalously low paramagnetic signal. The effects of vanadium substitution on the structure and transport properties of Li0.33MoO3 are dramatic. Attempts are made to correlate the observed electrical and magnetic behavior with the structure of Li0.33MoO3.",

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T1 - Substitutional studies on the anisotropic, semiconducting, molybdenum bronze, Li0.33MoO3

AU - Collins, B. T.

AU - Ramanujachary, Kandalam

AU - Greenblatt, M.

AU - McCarroll, W. H.

AU - McNally, P.

AU - Waszczak, J. V.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Pure Li0.33MoO3 and vanadium-doped Li0.33Mo1-xVxO3 crystals were grown by a temperature gradient flux technique. Directional electrical resistivity measurements have been made on both the pure and doped crystals. The electrical properties of Li0.33MoO3 are highly anisotropic with resistivity values at room temperature of 1.8 × 10-1 and 6.0 × 102 Ω cm along the c and b* directions, respectively. Li0.33 MoO3 shows complex semiconducting behavior and an anomalously low paramagnetic signal. The effects of vanadium substitution on the structure and transport properties of Li0.33MoO3 are dramatic. Attempts are made to correlate the observed electrical and magnetic behavior with the structure of Li0.33MoO3.

AB - Pure Li0.33MoO3 and vanadium-doped Li0.33Mo1-xVxO3 crystals were grown by a temperature gradient flux technique. Directional electrical resistivity measurements have been made on both the pure and doped crystals. The electrical properties of Li0.33MoO3 are highly anisotropic with resistivity values at room temperature of 1.8 × 10-1 and 6.0 × 102 Ω cm along the c and b* directions, respectively. Li0.33 MoO3 shows complex semiconducting behavior and an anomalously low paramagnetic signal. The effects of vanadium substitution on the structure and transport properties of Li0.33MoO3 are dramatic. Attempts are made to correlate the observed electrical and magnetic behavior with the structure of Li0.33MoO3.

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