Selective oxidation of primary silyl ethers and its application to the synthesis of natural products

A. Rodríguez, M. Nomen, B. W. Spur, J. J. Godfroid

Research output: Contribution to journalArticlepeer-review

110 Scopus citations

Abstract

Primary TMS or TES ethers, in the presence of secondary TMS or TES ethers, are selectively oxidized to the corresponding aldehydes under Swern conditions. A short synthesis of key intermediates towards various natural products has been achieved.

Original languageEnglish (US)
Pages (from-to)5161-5164
Number of pages4
JournalTetrahedron Letters
Volume40
Issue number28
DOIs
StatePublished - Jul 9 1999

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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