Room temperature self-healing thermoset based on the diels-alder reaction

Purnomo A. Pratama; Majid Sharifi; Amy M. Peterson; Giuseppe R. Palmese

doi:10.1021/am403459e

Room temperature self-healing thermoset based on the diels-alder reaction

Purnomo A. Pratama, Majid Sharifi, Amy M. Peterson, Giuseppe R. Palmese

Research output: Contribution to journal › Article › peer-review

124 Scopus citations

Abstract

A self-healing epoxy-amine thermoset based on the compatible functionalization of the thermoset and encapsulated healing agent has been successfully developed. Healing of the thermoset resulted from the reaction of furans in the thermoset and multimaleimides (MMIs) in the healing agent solution. The healing agent, MMI dissolved in phenyl acetate, was encapsulated using a urea-formaldehyde encapsulation method. Autonomic healing of the thermoset was achieved by incorporating microcapsules filled with the healing agent solution within a furan-functionalized epoxy-amine thermoset. The resulting self-healing thermoset recovered 71% of its initial load after fracture.

Original language	English (US)
Pages (from-to)	12425-12431
Number of pages	7
Journal	ACS Applied Materials and Interfaces
Volume	5
Issue number	23
DOIs	https://doi.org/10.1021/am403459e
State	Published - Dec 11 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

Materials Science(all)

Access to Document

10.1021/am403459e

Cite this

@article{39dbbb0c58d44899a68d414736316901,

title = "Room temperature self-healing thermoset based on the diels-alder reaction",

abstract = "A self-healing epoxy-amine thermoset based on the compatible functionalization of the thermoset and encapsulated healing agent has been successfully developed. Healing of the thermoset resulted from the reaction of furans in the thermoset and multimaleimides (MMIs) in the healing agent solution. The healing agent, MMI dissolved in phenyl acetate, was encapsulated using a urea-formaldehyde encapsulation method. Autonomic healing of the thermoset was achieved by incorporating microcapsules filled with the healing agent solution within a furan-functionalized epoxy-amine thermoset. The resulting self-healing thermoset recovered 71% of its initial load after fracture.",

author = "Pratama, {Purnomo A.} and Majid Sharifi and Peterson, {Amy M.} and Palmese, {Giuseppe R.}",

year = "2013",

month = dec,

day = "11",

doi = "10.1021/am403459e",

language = "English (US)",

volume = "5",

pages = "12425--12431",

journal = "ACS applied materials & interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - Room temperature self-healing thermoset based on the diels-alder reaction

AU - Pratama, Purnomo A.

AU - Sharifi, Majid

AU - Peterson, Amy M.

AU - Palmese, Giuseppe R.

PY - 2013/12/11

Y1 - 2013/12/11

N2 - A self-healing epoxy-amine thermoset based on the compatible functionalization of the thermoset and encapsulated healing agent has been successfully developed. Healing of the thermoset resulted from the reaction of furans in the thermoset and multimaleimides (MMIs) in the healing agent solution. The healing agent, MMI dissolved in phenyl acetate, was encapsulated using a urea-formaldehyde encapsulation method. Autonomic healing of the thermoset was achieved by incorporating microcapsules filled with the healing agent solution within a furan-functionalized epoxy-amine thermoset. The resulting self-healing thermoset recovered 71% of its initial load after fracture.

AB - A self-healing epoxy-amine thermoset based on the compatible functionalization of the thermoset and encapsulated healing agent has been successfully developed. Healing of the thermoset resulted from the reaction of furans in the thermoset and multimaleimides (MMIs) in the healing agent solution. The healing agent, MMI dissolved in phenyl acetate, was encapsulated using a urea-formaldehyde encapsulation method. Autonomic healing of the thermoset was achieved by incorporating microcapsules filled with the healing agent solution within a furan-functionalized epoxy-amine thermoset. The resulting self-healing thermoset recovered 71% of its initial load after fracture.

UR - http://www.scopus.com/inward/record.url?scp=84890534057&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84890534057&partnerID=8YFLogxK

U2 - 10.1021/am403459e

DO - 10.1021/am403459e

M3 - Article

AN - SCOPUS:84890534057

SN - 1944-8244

VL - 5

SP - 12425

EP - 12431

JO - ACS applied materials & interfaces

JF - ACS applied materials & interfaces

IS - 23

ER -

Room temperature self-healing thermoset based on the diels-alder reaction

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this