Rate coefficients for H+O2+CO2→HO2+CO2 determined in a new high pressure laminar flow reactor

F. M. Haas; T. I. Farouk; M. Chaos; M. P. Burke; F. L. Dryer

Rate coefficients for H+O₂+CO₂→HO₂+CO₂ determined in a new high pressure laminar flow reactor

F. M. Haas, T. I. Farouk, M. Chaos, M. P. Burke, F. L. Dryer

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

In practical combustion systems, CO₂ is present as a ubiquitous, high-concentration species present either in the unburned fuel gases or formed as the final product of fuel oxidation. There are comparatively few rate coefficient determinations for the important termolecular reaction H+O₂+M→HO₂+M, M = CO₂. Rate coefficients for M = CO₂ are measured in a new High Pressure Laminar Flow Reactor facility (HPLFR), previously validated with experimental measurements for M = N₂, Ar. Preliminary HPLFR measurements, considered with critically-reviewed literature rate coefficients of Ashman & Haynes and Vasu et al., suggest a CO₂ collisional efficiency relative to N₂ somewhat lower than the present relative efficiency of 3.8 employed in the kinetic model of Burke et al. (IJCK, in press).

Original language	English (US)
Title of host publication	Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011
Publisher	Combustion Institute
Pages	164-170
Number of pages	7
ISBN (Electronic)	9781622761258
State	Published - 2011
Externally published	Yes
Event	Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011 - Storrs, United States Duration: Oct 9 2011 → Oct 12 2011

Publication series

Name	Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011

Conference

Conference	Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011
Country/Territory	United States
City	Storrs
Period	10/9/11 → 10/12/11

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Mechanical Engineering
General Chemical Engineering

Cite this

Haas, F. M., Farouk, T. I., Chaos, M., Burke, M. P., & Dryer, F. L. (2011). Rate coefficients for H+O₂+CO₂→HO₂+CO₂ determined in a new high pressure laminar flow reactor. In Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011 (pp. 164-170). (Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011). Combustion Institute.

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title = "Rate coefficients for H+O2+CO2→HO2+CO2 determined in a new high pressure laminar flow reactor",

abstract = "In practical combustion systems, CO2 is present as a ubiquitous, high-concentration species present either in the unburned fuel gases or formed as the final product of fuel oxidation. There are comparatively few rate coefficient determinations for the important termolecular reaction H+O2+M→HO2+M, M = CO2. Rate coefficients for M = CO2 are measured in a new High Pressure Laminar Flow Reactor facility (HPLFR), previously validated with experimental measurements for M = N2, Ar. Preliminary HPLFR measurements, considered with critically-reviewed literature rate coefficients of Ashman & Haynes and Vasu et al., suggest a CO2 collisional efficiency relative to N2 somewhat lower than the present relative efficiency of 3.8 employed in the kinetic model of Burke et al. (IJCK, in press).",

author = "Haas, {F. M.} and Farouk, {T. I.} and M. Chaos and Burke, {M. P.} and Dryer, {F. L.}",

year = "2011",

language = "English (US)",

series = "Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011",

publisher = "Combustion Institute",

pages = "164--170",

booktitle = "Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011",

note = "Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011 ; Conference date: 09-10-2011 Through 12-10-2011",

}

Haas, FM, Farouk, TI, Chaos, M, Burke, MP & Dryer, FL 2011, Rate coefficients for H+O₂+CO₂→HO₂+CO₂ determined in a new high pressure laminar flow reactor. in Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011. Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011, Combustion Institute, pp. 164-170, Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011, Storrs, United States, 10/9/11.

Rate coefficients for H+O₂+CO₂→HO₂+CO₂ determined in a new high pressure laminar flow reactor. / Haas, F. M.; Farouk, T. I.; Chaos, M. et al.
Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011. Combustion Institute, 2011. p. 164-170 (Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Rate coefficients for H+O2+CO2→HO2+CO2 determined in a new high pressure laminar flow reactor

AU - Haas, F. M.

AU - Farouk, T. I.

AU - Chaos, M.

AU - Burke, M. P.

AU - Dryer, F. L.

PY - 2011

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N2 - In practical combustion systems, CO2 is present as a ubiquitous, high-concentration species present either in the unburned fuel gases or formed as the final product of fuel oxidation. There are comparatively few rate coefficient determinations for the important termolecular reaction H+O2+M→HO2+M, M = CO2. Rate coefficients for M = CO2 are measured in a new High Pressure Laminar Flow Reactor facility (HPLFR), previously validated with experimental measurements for M = N2, Ar. Preliminary HPLFR measurements, considered with critically-reviewed literature rate coefficients of Ashman & Haynes and Vasu et al., suggest a CO2 collisional efficiency relative to N2 somewhat lower than the present relative efficiency of 3.8 employed in the kinetic model of Burke et al. (IJCK, in press).

AB - In practical combustion systems, CO2 is present as a ubiquitous, high-concentration species present either in the unburned fuel gases or formed as the final product of fuel oxidation. There are comparatively few rate coefficient determinations for the important termolecular reaction H+O2+M→HO2+M, M = CO2. Rate coefficients for M = CO2 are measured in a new High Pressure Laminar Flow Reactor facility (HPLFR), previously validated with experimental measurements for M = N2, Ar. Preliminary HPLFR measurements, considered with critically-reviewed literature rate coefficients of Ashman & Haynes and Vasu et al., suggest a CO2 collisional efficiency relative to N2 somewhat lower than the present relative efficiency of 3.8 employed in the kinetic model of Burke et al. (IJCK, in press).

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PB - Combustion Institute

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