Preparation and transport properties of the substituted blue bronze (Rb1-xCsx)0.3MoO3

B. T. Collins; K. V. Ramanujachary; M. Greenblatt; J. V. Waszczak

doi:10.1016/0022-4596(88)90258-7

Preparation and transport properties of the substituted blue bronze (Rb_1-xCs_x)_0.3MoO₃

B. T. Collins, K. V. Ramanujachary, M. Greenblatt, J. V. Waszczak

Research output: Contribution to journal › Article › peer-review

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Abstract

Electrical and magnetic transport properties have been measured on single crystals of the molybdenum blue bronze alloy system (Rb_1-xCs_x)_0.3MoO₃ prepared by the temperature gradient flux technique. Although the properties of the blue bronze are retained, cesium substitution decreases both ρ{variant} (298 K) and the transition temperature observed at 180 K for Rb_0.3MoO₃. Solid-state studies indicate that the upper limit of Cs doping is approximately 45%. Attempts are made to correlate the effects of cesium substitution with the observed changes in the transport properties.

Original language	English (US)
Pages (from-to)	348-355
Number of pages	8
Journal	Journal of Solid State Chemistry
Volume	77
Issue number	2
DOIs	https://doi.org/10.1016/0022-4596(88)90258-7
State	Published - Dec 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-4596(88)90258-7

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title = "Preparation and transport properties of the substituted blue bronze (Rb1-xCsx)0.3MoO3",

abstract = "Electrical and magnetic transport properties have been measured on single crystals of the molybdenum blue bronze alloy system (Rb1-xCsx)0.3MoO3 prepared by the temperature gradient flux technique. Although the properties of the blue bronze are retained, cesium substitution decreases both ρ\{variant\} (298 K) and the transition temperature observed at 180 K for Rb0.3MoO3. Solid-state studies indicate that the upper limit of Cs doping is approximately 45\%. Attempts are made to correlate the effects of cesium substitution with the observed changes in the transport properties.",

author = "Collins, \{B. T.\} and Ramanujachary, \{K. V.\} and M. Greenblatt and Waszczak, \{J. V.\}",

note = "Funding Information: We gratefully acknowledge Mark Greaney for atomic absorption measurements. This research was supported by National Science Foundation Solid State Chemistry Grants DMR-84-04003 and DMR-87-14072 and National Science Foundation Materials Research Instrumentation Grants DMR-84-08266 and DMR-87-05620.",

year = "1988",

month = dec,

doi = "10.1016/0022-4596(88)90258-7",

language = "English (US)",

volume = "77",

pages = "348--355",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Preparation and transport properties of the substituted blue bronze (Rb1-xCsx)0.3MoO3

AU - Collins, B. T.

AU - Ramanujachary, K. V.

AU - Greenblatt, M.

AU - Waszczak, J. V.

N1 - Funding Information: We gratefully acknowledge Mark Greaney for atomic absorption measurements. This research was supported by National Science Foundation Solid State Chemistry Grants DMR-84-04003 and DMR-87-14072 and National Science Foundation Materials Research Instrumentation Grants DMR-84-08266 and DMR-87-05620.

PY - 1988/12

Y1 - 1988/12

N2 - Electrical and magnetic transport properties have been measured on single crystals of the molybdenum blue bronze alloy system (Rb1-xCsx)0.3MoO3 prepared by the temperature gradient flux technique. Although the properties of the blue bronze are retained, cesium substitution decreases both ρ{variant} (298 K) and the transition temperature observed at 180 K for Rb0.3MoO3. Solid-state studies indicate that the upper limit of Cs doping is approximately 45%. Attempts are made to correlate the effects of cesium substitution with the observed changes in the transport properties.

AB - Electrical and magnetic transport properties have been measured on single crystals of the molybdenum blue bronze alloy system (Rb1-xCsx)0.3MoO3 prepared by the temperature gradient flux technique. Although the properties of the blue bronze are retained, cesium substitution decreases both ρ{variant} (298 K) and the transition temperature observed at 180 K for Rb0.3MoO3. Solid-state studies indicate that the upper limit of Cs doping is approximately 45%. Attempts are made to correlate the effects of cesium substitution with the observed changes in the transport properties.

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JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Preparation and transport properties of the substituted blue bronze (Rb_1-xCs_x)_0.3MoO₃

Abstract

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