On the tetragonal forms of KMo4O6

W. H. McCarroll; K. V. Ramanujachary; M. Greenblatt; Richard E. Marsh

doi:10.1006/jssc.1995.1266

On the tetragonal forms of KMo₄O₆

W. H. McCarroll, K. V. Ramanujachary, M. Greenblatt, Richard E. Marsh

Chemistry

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9 Scopus citations

Abstract

A reexamination of the X-ray diffraction data for the tetragonal form of KMo₄O₆ prepared by fused salt electrolysis leads to the conclusion that the crystal structure is better described by using space group P 4/mbm and not P4̄ as previously reported. However, refinement in the new space group does not result in any significant changes in the atomic arrangement. Possible reasons for the significant difference between the c lattice parameter of this form of KMo₄O₆ and that prepared at high pressures are also discussed.

Original language	English (US)
Pages (from-to)	217-218
Number of pages	2
Journal	Journal of Solid State Chemistry
Volume	117
Issue number	1
DOIs	https://doi.org/10.1006/jssc.1995.1266
State	Published - Jun 1995

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1006/jssc.1995.1266

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AU - Greenblatt, M.

AU - Marsh, Richard E.

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AB - A reexamination of the X-ray diffraction data for the tetragonal form of KMo4O6 prepared by fused salt electrolysis leads to the conclusion that the crystal structure is better described by using space group P 4/mbm and not P4̄ as previously reported. However, refinement in the new space group does not result in any significant changes in the atomic arrangement. Possible reasons for the significant difference between the c lattice parameter of this form of KMo4O6 and that prepared at high pressures are also discussed.

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On the tetragonal forms of KMo₄O₆

Abstract

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