New double perovskites, LaBaTaNi1-xCoxO6: Structural, dielectric and magnetic studies

S. L. Samal, T. Magdaleno, K. V. Ramanujachary, S. E. Lofland, A. K. Ganguli

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    4 Scopus citations

    Abstract

    Double perovskites of the type LaBaNi1-xCoxTaO 6 (0 ≤ x ≤ 1) have been synthesized by solid state method. The compounds crystallize in the tetragonal space group, I4/m. Rietveld refinement has been carried out to determine the phase purity and to study the cation ordering. X-ray photoelectron spectroscopy confirms Co(II) in all compositions. The end members in LaBaNi1-xCoxTaO6 show high dielectric constant values. Antiferromagnetic ordering has been observed for all the compositions and the ordering temperature in LaBaNi1-xCo xTaO6 gradually decreases with increase in Co doping, which has been attributed to the decrease in covalence of Co/Ni-O bonds.

    Original languageEnglish (US)
    Pages (from-to)1382-1386
    Number of pages5
    JournalSolid State Sciences
    Volume12
    Issue number8
    DOIs
    StatePublished - Aug 2010

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

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