Miniemulsion synthesis of metal-oxo cluster containing copolymer nanobeads

Michele H. Pablico; Julie E. Mertzman; Emily A. Japp; William L. Boncher; Maki Nishida; Edward Van Keuren; Samuel E. Lofland; Norman Dollahon; Judith F. Rubinson; K. Travis Holman; Sarah L. Stoll

doi:10.1021/la2029774

Miniemulsion synthesis of metal-oxo cluster containing copolymer nanobeads

Michele H. Pablico, Julie E. Mertzman, Emily A. Japp, William L. Boncher, Maki Nishida, Edward Van Keuren, Samuel E. Lofland, Norman Dollahon, Judith F. Rubinson, K. Travis Holman, Sarah L. Stoll

Physics

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Hybrid nanobeads containing either a manganese-oxo or manganese-iron-oxo cluster have been prepared via the miniemulsion polymerization technique. Two new ligand substituted oxo clusters, Mn ₁₂O ₁₂(VBA) ₁₆(H ₂O) ₄ and Mn ₈Fe ₄O ₁₂(VBA) ₁₆(H ₂O) ₄ (where VBA = 4-vinylbenzoate), have been prepared and characterized. Polymerization of the functionalized metal-oxo clusters with styrene under miniemulsion conditions produced monodispersed polymer nanoparticles as small as ∼60 nm in diameter. The metal-oxo polymer nanobeads were fully characterized in terms of synthetic parameters, composition, structure, and magnetic properties.

Original language	English (US)
Pages (from-to)	12575-12584
Number of pages	10
Journal	Langmuir
Volume	27
Issue number	20
DOIs	https://doi.org/10.1021/la2029774
State	Published - Oct 18 2011

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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10.1021/la2029774

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@article{d86aae7a659542618c0be6e5dff92907,

title = "Miniemulsion synthesis of metal-oxo cluster containing copolymer nanobeads",

abstract = "Hybrid nanobeads containing either a manganese-oxo or manganese-iron-oxo cluster have been prepared via the miniemulsion polymerization technique. Two new ligand substituted oxo clusters, Mn 12O 12(VBA) 16(H 2O) 4 and Mn 8Fe 4O 12(VBA) 16(H 2O) 4 (where VBA = 4-vinylbenzoate), have been prepared and characterized. Polymerization of the functionalized metal-oxo clusters with styrene under miniemulsion conditions produced monodispersed polymer nanoparticles as small as ∼60 nm in diameter. The metal-oxo polymer nanobeads were fully characterized in terms of synthetic parameters, composition, structure, and magnetic properties.",

author = "Pablico, {Michele H.} and Mertzman, {Julie E.} and Japp, {Emily A.} and Boncher, {William L.} and Maki Nishida and {Van Keuren}, Edward and Lofland, {Samuel E.} and Norman Dollahon and Rubinson, {Judith F.} and Holman, {K. Travis} and Stoll, {Sarah L.}",

year = "2011",

month = oct,

day = "18",

doi = "10.1021/la2029774",

language = "English (US)",

volume = "27",

pages = "12575--12584",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Miniemulsion synthesis of metal-oxo cluster containing copolymer nanobeads

AU - Pablico, Michele H.

AU - Mertzman, Julie E.

AU - Japp, Emily A.

AU - Boncher, William L.

AU - Nishida, Maki

AU - Van Keuren, Edward

AU - Lofland, Samuel E.

AU - Dollahon, Norman

AU - Rubinson, Judith F.

AU - Holman, K. Travis

AU - Stoll, Sarah L.

PY - 2011/10/18

Y1 - 2011/10/18

N2 - Hybrid nanobeads containing either a manganese-oxo or manganese-iron-oxo cluster have been prepared via the miniemulsion polymerization technique. Two new ligand substituted oxo clusters, Mn 12O 12(VBA) 16(H 2O) 4 and Mn 8Fe 4O 12(VBA) 16(H 2O) 4 (where VBA = 4-vinylbenzoate), have been prepared and characterized. Polymerization of the functionalized metal-oxo clusters with styrene under miniemulsion conditions produced monodispersed polymer nanoparticles as small as ∼60 nm in diameter. The metal-oxo polymer nanobeads were fully characterized in terms of synthetic parameters, composition, structure, and magnetic properties.

AB - Hybrid nanobeads containing either a manganese-oxo or manganese-iron-oxo cluster have been prepared via the miniemulsion polymerization technique. Two new ligand substituted oxo clusters, Mn 12O 12(VBA) 16(H 2O) 4 and Mn 8Fe 4O 12(VBA) 16(H 2O) 4 (where VBA = 4-vinylbenzoate), have been prepared and characterized. Polymerization of the functionalized metal-oxo clusters with styrene under miniemulsion conditions produced monodispersed polymer nanoparticles as small as ∼60 nm in diameter. The metal-oxo polymer nanobeads were fully characterized in terms of synthetic parameters, composition, structure, and magnetic properties.

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U2 - 10.1021/la2029774

DO - 10.1021/la2029774

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AN - SCOPUS:80053948595

SN - 0743-7463

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SP - 12575

EP - 12584

JO - Langmuir

JF - Langmuir

IS - 20

ER -

Miniemulsion synthesis of metal-oxo cluster containing copolymer nanobeads

Abstract

All Science Journal Classification (ASJC) codes

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