Magnetic and structural studies of the multifunctional material SrFe 0.75Mo 0.25O 3-δ

M. Retuerto, M. R. Li, Y. B. Go, A. Ignatov, M. Croft, K. V. Ramanujachary, J. Hadermann, J. P. Hodges, R. H. Herber, I. Nowik, M. Greenblatt

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Abstract

SrFe 0.75Mo 0.25O 3-δ has been recently discovered as an extremely efficient electrode for intermediate temperature solid oxide fuel cells (IT-SOFCs). We have performed structural and magnetic studies to fully characterize this multifunctional material. We have observed by powder neutron diffraction (PND) and transmission electron microscopy (TEM) that its crystal symmetry is better explained with a tetragonal symmetry (I4/mcm space group) than with the previously reported orthorhombic symmetry (Pnma space group). The temperature dependent magnetic properties indicate an exceptionally high magnetic ordering temperature (T N ∼ 750 K), well above room temperature. The ordered magnetic structure at low temperature was determined by PND to be an antiferromagnetic coupling of the Fe cations. Mössbauer spectroscopy corroborated the PND results. A detailed study, with X-ray absorption spectroscopy (XAS), in agreement with the Mössbauer results, confirmed the formal oxidation states of the cations to be mixed valence Fe 3+/4+ and Mo 6+.

Original languageEnglish (US)
Pages (from-to)12273-12280
Number of pages8
JournalInorganic Chemistry
Volume51
Issue number22
DOIs
StatePublished - Nov 19 2012

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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