Abstract
Structural information on pulsed plasma-polymerized fluorocarbon films was obtained using high resolution 19F MAS NMR spectroscopy. Fluorocarbon sequences of up to three carbon bond lengths were identified and relative amounts quantified. Pulsing and HFPO plasma at longer off-times facilitated linear chain propagation and resulted in films with less heterogeneous bonding environments. Also, thermal decomposition shifted from a loss of CF3 terminations to a loss of linear chain fragments.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 936-937 |
| Number of pages | 2 |
| Journal | American Chemical Society, Polymer Preprints, Division of Polymer Chemistry |
| Volume | 39 |
| Issue number | 2 |
| State | Published - Aug 1998 |
| Externally published | Yes |
| Event | Proceedings of the 1997 Boston Meeting - Boston, MA, USA Duration: Aug 23 1998 → Aug 27 1998 |
All Science Journal Classification (ASJC) codes
- Polymers and Plastics