TY - JOUR
T1 - Formation of high nuclearity mixed-valent polyoxovanadates in the presence of copper amine complexes
AU - Thomas, Jency
AU - Sharma, Sanjeev
AU - Lofland, S. E.
AU - Ramanujachary, K. V.
AU - Ramanan, A.
N1 - Funding Information:
JT acknowledges CSIR fofre lalowship. ARc kanow-16.Müller A, Krickemeyer E, Penk M, Rohlfinrgm Ra-, ABogge H 198A7ngewC. hem. Int. Ed. E.n2g6l1045 ledgesDST for financial support and-IRDHSPTA tageA and Bogge H19 91Angew. Chem. Int. Ed. and DS-TFIST for the powder and single crystal XEngl. 301674 ray diffraction facility to Department osft rCyh, e17.miBrown I D and Altermatt D 1A9c8ta5 Crystallo.g r IIT, Delhi. AR, KVR and SEL express tehsepier crt B41244 and admiration to Prof J Gopsahlankarni whosen c-oXuebao2353518.Lin B Z and Liu S X 20G02ao deng Xuexiao Huaxue tributions have enriched our unddinegrs toafn the19.Cui X B, Zheng S T, DingD Lin,g H and Yang G Y fascinating chemistry of inorganic solids. 2003J iegou Huaxu2e2491 20. Müller A, Sessoli R, Krickemeyer E, Bogge H,
Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.
PY - 2006/1
Y1 - 2006/1
N2 - Two new Müller-type clusters, a one-dimensional solid {Cu(en) 2} 4[Cl ⊂ V 15O 36]·12H 2O 1, and a three-dimensional solid [Cu(pn) 2} 4[Cl ⊂ V 18O 42]·12H 2O 2, have been synthesised by employing identical hydrothermal conditions except varying the nature of organic diamine. 1 crystallised in a chiral space group P2 12 12 1 with a = 12·757(1), b = 18·927(2) and c = 28·590(3) Å, and Z = 4. 2 crystallised in a tetragonal system with space group P4/nnc, a = 15·113(1) and c = 18·542(3) Å, and Z= 2. Mixed-valent vanadium ions in structures 1 and 2 have been established both by magnetisation and bond-length bondvalence measurements. Chemistry of formation of high nuclearity polyoxovanadate clusters is discussed.
AB - Two new Müller-type clusters, a one-dimensional solid {Cu(en) 2} 4[Cl ⊂ V 15O 36]·12H 2O 1, and a three-dimensional solid [Cu(pn) 2} 4[Cl ⊂ V 18O 42]·12H 2O 2, have been synthesised by employing identical hydrothermal conditions except varying the nature of organic diamine. 1 crystallised in a chiral space group P2 12 12 1 with a = 12·757(1), b = 18·927(2) and c = 28·590(3) Å, and Z = 4. 2 crystallised in a tetragonal system with space group P4/nnc, a = 15·113(1) and c = 18·542(3) Å, and Z= 2. Mixed-valent vanadium ions in structures 1 and 2 have been established both by magnetisation and bond-length bondvalence measurements. Chemistry of formation of high nuclearity polyoxovanadate clusters is discussed.
UR - https://www.scopus.com/pages/publications/33144473885
UR - https://www.scopus.com/pages/publications/33144473885#tab=citedBy
U2 - 10.1007/BF02708768
DO - 10.1007/BF02708768
M3 - Article
AN - SCOPUS:33144473885
SN - 0253-4134
VL - 118
SP - 79
EP - 86
JO - Proceedings of the Indian Academy of Sciences: Chemical Sciences
JF - Proceedings of the Indian Academy of Sciences: Chemical Sciences
IS - 1
ER -