@article{e81c3d2e3c22432384090f62e39a405e,
title = "Formation of high nuclearity mixed-valent polyoxovanadates in the presence of copper amine complexes",
abstract = "Two new M{\"u}ller-type clusters, a one-dimensional solid {Cu(en) 2} 4[Cl ⊂ V 15O 36]·12H 2O 1, and a three-dimensional solid [Cu(pn) 2} 4[Cl ⊂ V 18O 42]·12H 2O 2, have been synthesised by employing identical hydrothermal conditions except varying the nature of organic diamine. 1 crystallised in a chiral space group P2 12 12 1 with a = 12·757(1), b = 18·927(2) and c = 28·590(3) {\AA}, and Z = 4. 2 crystallised in a tetragonal system with space group P4/nnc, a = 15·113(1) and c = 18·542(3) {\AA}, and Z= 2. Mixed-valent vanadium ions in structures 1 and 2 have been established both by magnetisation and bond-length bondvalence measurements. Chemistry of formation of high nuclearity polyoxovanadate clusters is discussed.",
author = "Jency Thomas and Sanjeev Sharma and Lofland, {S. E.} and Ramanujachary, {K. V.} and A. Ramanan",
note = "Funding Information: JT acknowledges CSIR fofre lalowship. ARc kanow-16.M{\"u}ller A, Krickemeyer E, Penk M, Rohlfinrgm Ra-, ABogge H 198A7ngewC. hem. Int. Ed. E.n2g6l1045 ledgesDST for financial support and-IRDHSPTA tageA and Bogge H19 91Angew. Chem. Int. Ed. and DS-TFIST for the powder and single crystal XEngl. 301674 ray diffraction facility to Department osft rCyh, e17.miBrown I D and Altermatt D 1A9c8ta5 Crystallo.g r IIT, Delhi. AR, KVR and SEL express tehsepier crt B41244 and admiration to Prof J Gopsahlankarni whosen c-oXuebao2353518.Lin B Z and Liu S X 20G02ao deng Xuexiao Huaxue tributions have enriched our unddinegrs toafn the19.Cui X B, Zheng S T, DingD Lin,g H and Yang G Y fascinating chemistry of inorganic solids. 2003J iegou Huaxu2e2491 20. M{\"u}ller A, Sessoli R, Krickemeyer E, Bogge H, Copyright: Copyright 2011 Elsevier B.V., All rights reserved.",
year = "2006",
month = jan,
doi = "10.1007/BF02708768",
language = "English (US)",
volume = "118",
pages = "79--86",
journal = "Journal of Chemical Sciences",
issn = "0253-4134",
publisher = "Indian Academy of Sciences",
number = "1",
}