Design of non-molecular coordination solids from aqueous solution: [CuIILnX(H2O)], where X=SO4, Cl or H2O and L=pyrazole, imidazole or glutamic acid and n=1 or 4

Vineet Kumar; Aritra Kundu; Monika Singh; Kandalam V. Ramanujachary; Arunachalam Ramanan

doi:10.1007/s12039-014-0678-9

Design of non-molecular coordination solids from aqueous solution: [Cu^IIL_nX(H₂O)], where X=SO₄, Cl or H₂O and L=pyrazole, imidazole or glutamic acid and n=1 or 4

Vineet Kumar, Aritra Kundu, Monika Singh, Kandalam V. Ramanujachary, Arunachalam Ramanan

Chemistry

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Abstract

We have successfully crystallized four new non-molecular coordination solids utilizing the synthons-Cu-OSO₃- and -Cu-Cl- in the presence of four organic ligands:[{Cu(pz)₄SO₄}{Cu(pz)₄SO₄ (H₂O)}]. H₂O2, [Cu(imi)₄SO₄]3, [Cu(imi)₄(NO₃)₂]4 and [Cu(glu)Cl(H₂O)]5. Use of glutamic acid resulted in two chiral coordination polymers 5 and [Cu(glu)(H₂O)]. H₂O 6 depending on the copper source. The paper provides chemical insights to the supramolecular aggregation of a crystal driven by the various competing intermolecular forces.

Original language	English (US)
Pages (from-to)	1433-1442
Number of pages	10
Journal	Journal of Chemical Sciences
Volume	126
Issue number	5
DOIs	https://doi.org/10.1007/s12039-014-0678-9
State	Published - Sep 2014

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General Chemistry

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title = "Design of non-molecular coordination solids from aqueous solution: [CuIILnX(H2O)], where X=SO4, Cl or H2O and L=pyrazole, imidazole or glutamic acid and n=1 or 4",

abstract = "We have successfully crystallized four new non-molecular coordination solids utilizing the synthons-Cu-OSO3- and -Cu-Cl- in the presence of four organic ligands:[{Cu(pz)4SO4}{Cu(pz)4SO4 (H2O)}]. H2O2, [Cu(imi)4SO4]3, [Cu(imi)4(NO3)2]4 and [Cu(glu)Cl(H2O)]5. Use of glutamic acid resulted in two chiral coordination polymers 5 and [Cu(glu)(H2O)]. H2O 6 depending on the copper source. The paper provides chemical insights to the supramolecular aggregation of a crystal driven by the various competing intermolecular forces.",

author = "Vineet Kumar and Aritra Kundu and Monika Singh and Ramanujachary, {Kandalam V.} and Arunachalam Ramanan",

note = "Publisher Copyright: {\textcopyright} 2014 Indian Academy of Sciences.",

year = "2014",

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doi = "10.1007/s12039-014-0678-9",

language = "English (US)",

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T1 - Design of non-molecular coordination solids from aqueous solution

T2 - [CuIILnX(H2O)], where X=SO4, Cl or H2O and L=pyrazole, imidazole or glutamic acid and n=1 or 4

AU - Kumar, Vineet

AU - Kundu, Aritra

AU - Singh, Monika

AU - Ramanujachary, Kandalam V.

AU - Ramanan, Arunachalam

PY - 2014/9

Y1 - 2014/9

N2 - We have successfully crystallized four new non-molecular coordination solids utilizing the synthons-Cu-OSO3- and -Cu-Cl- in the presence of four organic ligands:[{Cu(pz)4SO4}{Cu(pz)4SO4 (H2O)}]. H2O2, [Cu(imi)4SO4]3, [Cu(imi)4(NO3)2]4 and [Cu(glu)Cl(H2O)]5. Use of glutamic acid resulted in two chiral coordination polymers 5 and [Cu(glu)(H2O)]. H2O 6 depending on the copper source. The paper provides chemical insights to the supramolecular aggregation of a crystal driven by the various competing intermolecular forces.

AB - We have successfully crystallized four new non-molecular coordination solids utilizing the synthons-Cu-OSO3- and -Cu-Cl- in the presence of four organic ligands:[{Cu(pz)4SO4}{Cu(pz)4SO4 (H2O)}]. H2O2, [Cu(imi)4SO4]3, [Cu(imi)4(NO3)2]4 and [Cu(glu)Cl(H2O)]5. Use of glutamic acid resulted in two chiral coordination polymers 5 and [Cu(glu)(H2O)]. H2O 6 depending on the copper source. The paper provides chemical insights to the supramolecular aggregation of a crystal driven by the various competing intermolecular forces.

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JO - Journal of Chemical Sciences

JF - Journal of Chemical Sciences

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Design of non-molecular coordination solids from aqueous solution: [Cu^IIL_nX(H₂O)], where X=SO₄, Cl or H₂O and L=pyrazole, imidazole or glutamic acid and n=1 or 4

Abstract

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