Amino acid based mofs: Synthesis, structure, single crystal to single crystal transformation, Magnetic and related studies in a family of cobalt and nickel aminoisophthales

Debajit Sarma; K. V. Ramanujachary; S. E. Lofland; Travis Magdaleno; Srinivasan Natarajan

doi:10.1021/ic901678c

Amino acid based mofs: Synthesis, structure, single crystal to single crystal transformation, Magnetic and related studies in a family of cobalt and nickel aminoisophthales

Debajit Sarma
, K. V. Ramanujachary
, S. E. Lofland
, Travis Magdaleno
, Srinivasan Natarajan

Physics

Research output: Contribution to journal › Article › peer-review

124 Scopus citations

Abstract

Four new 5-aminoisophthalates of cobalt and nickel have been prepared employing hydro/solvothermal methods: [Co₂(C₈H ₅NO₄)₂(C₄H₄N ₂)(H₂O)₂] 3H₂O (I), [Ni ₂(C₈H₅NO₄)₂(C ₄H₄N₂)(H₂O)₂]· 3H₂O (II), [Co₂(H₂O)(μ³-OH) ₂-(C₈H₅NO₄)] (III), and [Ni ₂(H₂O)(μ-OH)₂(C₈H ₅NO₄)] (IV). Compounds I and II are isostructural, having aniondeficient CdCl₂ related layers bridged by a pyrazine ligand, giving rise to a bilayer arrangement. Compounds III and IV have one-dimensional M-O(H)-M chains connected by the 5-aminoisophthalate units forming a three-dimensional structure. The coordinated as well as the lattice water molecules of I and II could be removed and inserted by simple heating-cooling cycles under the atmospheric conditions. The removal of the coordinated water molecule is accompanied by changes in the coordination environment around the M²⁺ (M = Co, Ni) and color of the samples (purple to blue, Co; green to dark yellow, Ni). This change has been examined by a variety of techniques that include in situ single crystal to single crystal transformation studies and in situ IR and UV-vis spectroscopic studies. Magnetic studies indicate antiferromagnetic behavior in I and II, a field-induced magnetism in III, and a canted antiferromagnetic behavior in IV.

Original language	English (US)
Pages (from-to)	11660-11676
Number of pages	17
Journal	Inorganic Chemistry
Volume	48
Issue number	24
DOIs	https://doi.org/10.1021/ic901678c
State	Published - Dec 21 2009

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic901678c

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@article{c71759ca49054708937101ff208eec22,

title = "Amino acid based mofs: Synthesis, structure, single crystal to single crystal transformation, Magnetic and related studies in a family of cobalt and nickel aminoisophthales",

abstract = "Four new 5-aminoisophthalates of cobalt and nickel have been prepared employing hydro/solvothermal methods: [Co2(C8H 5NO4)2(C4H4N 2)(H2O)2] 3H2O (I), [Ni 2(C8H5NO4)2(C 4H4N2)(H2O)2]· 3H2O (II), [Co2(H2O)(μ3-OH) 2-(C8H5NO4)] (III), and [Ni 2(H2O)(μ-OH)2(C8H 5NO4)] (IV). Compounds I and II are isostructural, having aniondeficient CdCl2 related layers bridged by a pyrazine ligand, giving rise to a bilayer arrangement. Compounds III and IV have one-dimensional M-O(H)-M chains connected by the 5-aminoisophthalate units forming a three-dimensional structure. The coordinated as well as the lattice water molecules of I and II could be removed and inserted by simple heating-cooling cycles under the atmospheric conditions. The removal of the coordinated water molecule is accompanied by changes in the coordination environment around the M2+ (M = Co, Ni) and color of the samples (purple to blue, Co; green to dark yellow, Ni). This change has been examined by a variety of techniques that include in situ single crystal to single crystal transformation studies and in situ IR and UV-vis spectroscopic studies. Magnetic studies indicate antiferromagnetic behavior in I and II, a field-induced magnetism in III, and a canted antiferromagnetic behavior in IV.",

author = "Debajit Sarma and Ramanujachary, \{K. V.\} and Lofland, \{S. E.\} and Travis Magdaleno and Srinivasan Natarajan",

year = "2009",

month = dec,

day = "21",

doi = "10.1021/ic901678c",

language = "English (US)",

volume = "48",

pages = "11660--11676",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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}

Amino acid based mofs: Synthesis, structure, single crystal to single crystal transformation, Magnetic and related studies in a family of cobalt and nickel aminoisophthales. / Sarma, Debajit; Ramanujachary, K. V.; Lofland, S. E. et al.
In: Inorganic Chemistry, Vol. 48, No. 24, 21.12.2009, p. 11660-11676.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Amino acid based mofs

T2 - Synthesis, structure, single crystal to single crystal transformation, Magnetic and related studies in a family of cobalt and nickel aminoisophthales

AU - Sarma, Debajit

AU - Ramanujachary, K. V.

AU - Lofland, S. E.

AU - Magdaleno, Travis

AU - Natarajan, Srinivasan

PY - 2009/12/21

Y1 - 2009/12/21

N2 - Four new 5-aminoisophthalates of cobalt and nickel have been prepared employing hydro/solvothermal methods: [Co2(C8H 5NO4)2(C4H4N 2)(H2O)2] 3H2O (I), [Ni 2(C8H5NO4)2(C 4H4N2)(H2O)2]· 3H2O (II), [Co2(H2O)(μ3-OH) 2-(C8H5NO4)] (III), and [Ni 2(H2O)(μ-OH)2(C8H 5NO4)] (IV). Compounds I and II are isostructural, having aniondeficient CdCl2 related layers bridged by a pyrazine ligand, giving rise to a bilayer arrangement. Compounds III and IV have one-dimensional M-O(H)-M chains connected by the 5-aminoisophthalate units forming a three-dimensional structure. The coordinated as well as the lattice water molecules of I and II could be removed and inserted by simple heating-cooling cycles under the atmospheric conditions. The removal of the coordinated water molecule is accompanied by changes in the coordination environment around the M2+ (M = Co, Ni) and color of the samples (purple to blue, Co; green to dark yellow, Ni). This change has been examined by a variety of techniques that include in situ single crystal to single crystal transformation studies and in situ IR and UV-vis spectroscopic studies. Magnetic studies indicate antiferromagnetic behavior in I and II, a field-induced magnetism in III, and a canted antiferromagnetic behavior in IV.

AB - Four new 5-aminoisophthalates of cobalt and nickel have been prepared employing hydro/solvothermal methods: [Co2(C8H 5NO4)2(C4H4N 2)(H2O)2] 3H2O (I), [Ni 2(C8H5NO4)2(C 4H4N2)(H2O)2]· 3H2O (II), [Co2(H2O)(μ3-OH) 2-(C8H5NO4)] (III), and [Ni 2(H2O)(μ-OH)2(C8H 5NO4)] (IV). Compounds I and II are isostructural, having aniondeficient CdCl2 related layers bridged by a pyrazine ligand, giving rise to a bilayer arrangement. Compounds III and IV have one-dimensional M-O(H)-M chains connected by the 5-aminoisophthalate units forming a three-dimensional structure. The coordinated as well as the lattice water molecules of I and II could be removed and inserted by simple heating-cooling cycles under the atmospheric conditions. The removal of the coordinated water molecule is accompanied by changes in the coordination environment around the M2+ (M = Co, Ni) and color of the samples (purple to blue, Co; green to dark yellow, Ni). This change has been examined by a variety of techniques that include in situ single crystal to single crystal transformation studies and in situ IR and UV-vis spectroscopic studies. Magnetic studies indicate antiferromagnetic behavior in I and II, a field-induced magnetism in III, and a canted antiferromagnetic behavior in IV.

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UR - https://www.scopus.com/pages/publications/73249116871#tab=citedBy

U2 - 10.1021/ic901678c

DO - 10.1021/ic901678c

M3 - Article

C2 - 19938871

AN - SCOPUS:73249116871

SN - 0020-1669

VL - 48

SP - 11660

EP - 11676

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Amino acid based mofs: Synthesis, structure, single crystal to single crystal transformation, Magnetic and related studies in a family of cobalt and nickel aminoisophthales

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