Amino acid based mofs: Synthesis, structure, single crystal to single crystal transformation, Magnetic and related studies in a family of cobalt and nickel aminoisophthales

Debajit Sarma, K. V. Ramanujachary, S. E. Lofland, Travis Magdaleno, Srinivasan Natarajan

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Abstract

Four new 5-aminoisophthalates of cobalt and nickel have been prepared employing hydro/solvothermal methods: [Co2(C8H 5NO4)2(C4H4N 2)(H2O)2] 3H2O (I), [Ni 2(C8H5NO4)2(C 4H4N2)(H2O)2]· 3H2O (II), [Co2(H2O)(μ3-OH) 2-(C8H5NO4)] (III), and [Ni 2(H2O)(μ-OH)2(C8H 5NO4)] (IV). Compounds I and II are isostructural, having aniondeficient CdCl2 related layers bridged by a pyrazine ligand, giving rise to a bilayer arrangement. Compounds III and IV have one-dimensional M-O(H)-M chains connected by the 5-aminoisophthalate units forming a three-dimensional structure. The coordinated as well as the lattice water molecules of I and II could be removed and inserted by simple heating-cooling cycles under the atmospheric conditions. The removal of the coordinated water molecule is accompanied by changes in the coordination environment around the M2+ (M = Co, Ni) and color of the samples (purple to blue, Co; green to dark yellow, Ni). This change has been examined by a variety of techniques that include in situ single crystal to single crystal transformation studies and in situ IR and UV-vis spectroscopic studies. Magnetic studies indicate antiferromagnetic behavior in I and II, a field-induced magnetism in III, and a canted antiferromagnetic behavior in IV.

Original languageEnglish (US)
Pages (from-to)11660-11676
Number of pages17
JournalInorganic Chemistry
Volume48
Issue number24
DOIs
StatePublished - Dec 21 2009

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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