TY - CHAP
T1 - Allylboration
AU - Jonnalagadda, Subash C.
AU - Suman, Pathi
AU - Patel, Amardeep
AU - Jampana, Gayathri
AU - Colfer, Alexander
N1 - Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016
Y1 - 2016
N2 - Allylboration involves the addition of "allyl" boron species across multiple bonds (most commonly aldehydes, ketones, and imines). This chapter will focus on the recent advances in the area of stereoselective allylboration with a main emphasis on the boranes derived from chiral auxiliaries such as α-pinene, tartrate, borabicylo[3.3.2]decane, and camphor. Other topics include catalytic enantioselective allylboration and the chemistry of chiral αsubstituted allylboranes. Allylboration of other functional groups including epoxides, nitriles, lactams, and heteroaromatics are also discussed.
AB - Allylboration involves the addition of "allyl" boron species across multiple bonds (most commonly aldehydes, ketones, and imines). This chapter will focus on the recent advances in the area of stereoselective allylboration with a main emphasis on the boranes derived from chiral auxiliaries such as α-pinene, tartrate, borabicylo[3.3.2]decane, and camphor. Other topics include catalytic enantioselective allylboration and the chemistry of chiral αsubstituted allylboranes. Allylboration of other functional groups including epoxides, nitriles, lactams, and heteroaromatics are also discussed.
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U2 - 10.1021/bk-2016-1236.ch003
DO - 10.1021/bk-2016-1236.ch003
M3 - Chapter
AN - SCOPUS:85006018079
T3 - ACS Symposium Series
SP - 67
EP - 122
BT - Boron Reagents in Synthesis
A2 - Coca, Adiel
PB - American Chemical Society
ER -