Allylboration

Subash C. Jonnalagadda, Pathi Suman, Amardeep Patel, Gayathri Jampana, Alexander Colfer

Research output: Chapter in Book/Report/Conference proceedingChapter

2 Scopus citations

Abstract

Allylboration involves the addition of "allyl" boron species across multiple bonds (most commonly aldehydes, ketones, and imines). This chapter will focus on the recent advances in the area of stereoselective allylboration with a main emphasis on the boranes derived from chiral auxiliaries such as α-pinene, tartrate, borabicylo[3.3.2]decane, and camphor. Other topics include catalytic enantioselective allylboration and the chemistry of chiral αsubstituted allylboranes. Allylboration of other functional groups including epoxides, nitriles, lactams, and heteroaromatics are also discussed.

Original languageEnglish (US)
Title of host publicationBoron Reagents in Synthesis
EditorsAdiel Coca
PublisherAmerican Chemical Society
Pages67-122
Number of pages56
ISBN (Electronic)9780841231832
DOIs
StatePublished - Jan 1 2016

Publication series

NameACS Symposium Series
Volume1236
ISSN (Print)0097-6156
ISSN (Electronic)1947-5918

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Jonnalagadda, S. C., Suman, P., Patel, A., Jampana, G., & Colfer, A. (2016). Allylboration. In A. Coca (Ed.), Boron Reagents in Synthesis (pp. 67-122). (ACS Symposium Series; Vol. 1236). American Chemical Society. https://doi.org/10.1021/bk-2016-1236.ch003