A soluble fluorous palladium complex that promotes heck reactions and can be recovered and reused

Dennis P. Curran; Karin Fischer; Gustavo Moura-Letts

doi:10.1055/s-2004-829094

A soluble fluorous palladium complex that promotes heck reactions and can be recovered and reused

Dennis P. Curran, Karin Fischer, Gustavo Moura-Letts

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A new fluorous SCS pincer palladium complex is synthesized and shown to efficiently promote typical Heck reactions under microwave or thermal heating. The complex is air stable and can be recovered after reactions for reuse by fluorous solid phase extraction. By analogy to related complexes, it may function as a precursor of soluble ligandless palladium metal.

Original language	English (US)
Pages (from-to)	1379-1382
Number of pages	4
Journal	Synlett
Issue number	8
DOIs	https://doi.org/10.1055/s-2004-829094
State	Published - Jul 1 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-2004-829094

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abstract = "A new fluorous SCS pincer palladium complex is synthesized and shown to efficiently promote typical Heck reactions under microwave or thermal heating. The complex is air stable and can be recovered after reactions for reuse by fluorous solid phase extraction. By analogy to related complexes, it may function as a precursor of soluble ligandless palladium metal.",

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N2 - A new fluorous SCS pincer palladium complex is synthesized and shown to efficiently promote typical Heck reactions under microwave or thermal heating. The complex is air stable and can be recovered after reactions for reuse by fluorous solid phase extraction. By analogy to related complexes, it may function as a precursor of soluble ligandless palladium metal.

AB - A new fluorous SCS pincer palladium complex is synthesized and shown to efficiently promote typical Heck reactions under microwave or thermal heating. The complex is air stable and can be recovered after reactions for reuse by fluorous solid phase extraction. By analogy to related complexes, it may function as a precursor of soluble ligandless palladium metal.

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A soluble fluorous palladium complex that promotes heck reactions and can be recovered and reused

Abstract

All Science Journal Classification (ASJC) codes

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