A novel one-pot metathesis route for the synthesis of double perovskites, Ba3MM′2O9 (M = Mg, Ni, Zn; M′ = Nb, Ta) with 1: 2 ordering of M and M′ atoms

Rohini Mani; N. S.P. Bhuvanesh; K. V. Ramanujachary; William Green; S. E. Lofland; J. Gopalakrishnan

doi:10.1039/b616238j

A novel one-pot metathesis route for the synthesis of double perovskites, Ba₃MM′₂O₉ (M = Mg, Ni, Zn; M′ = Nb, Ta) with 1: 2 ordering of M and M′ atoms

Rohini Mani, N. S.P. Bhuvanesh, K. V. Ramanujachary, William Green, S. E. Lofland, J. Gopalakrishnan

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Solid state reaction of Li₂CO₃, MC₂O ₄·2H₂O (M = Mg, Ni, Zn), M′₂O ₅ (M′ = Nb, Ta) and BaCl₂ in stoichiometric quantities at 900-1100 °C in air provides a convenient one-pot synthesis route for 1: 2 B-site ordered double perovskite oxides, Ba₃MM′ ₂O₉, that find application in microwave telecommunications.

Original language	English (US)
Pages (from-to)	1589-1592
Number of pages	4
Journal	Journal of Materials Chemistry
Volume	17
Issue number	16
DOIs	https://doi.org/10.1039/b616238j
State	Published - 2007

All Science Journal Classification (ASJC) codes

General Chemistry
Materials Chemistry

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title = "A novel one-pot metathesis route for the synthesis of double perovskites, Ba3MM′2O9 (M = Mg, Ni, Zn; M′ = Nb, Ta) with 1: 2 ordering of M and M′ atoms",

abstract = "Solid state reaction of Li2CO3, MC2O 4·2H2O (M = Mg, Ni, Zn), M′2O 5 (M′ = Nb, Ta) and BaCl2 in stoichiometric quantities at 900-1100 °C in air provides a convenient one-pot synthesis route for 1: 2 B-site ordered double perovskite oxides, Ba3MM′ 2O9, that find application in microwave telecommunications.",

author = "Rohini Mani and Bhuvanesh, {N. S.P.} and Ramanujachary, {K. V.} and William Green and Lofland, {S. E.} and J. Gopalakrishnan",

year = "2007",

doi = "10.1039/b616238j",

language = "English (US)",

volume = "17",

pages = "1589--1592",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - A novel one-pot metathesis route for the synthesis of double perovskites, Ba3MM′2O9 (M = Mg, Ni, Zn; M′ = Nb, Ta) with 1

T2 - 2 ordering of M and M′ atoms

AU - Mani, Rohini

AU - Bhuvanesh, N. S.P.

AU - Ramanujachary, K. V.

AU - Green, William

AU - Lofland, S. E.

AU - Gopalakrishnan, J.

PY - 2007

Y1 - 2007

N2 - Solid state reaction of Li2CO3, MC2O 4·2H2O (M = Mg, Ni, Zn), M′2O 5 (M′ = Nb, Ta) and BaCl2 in stoichiometric quantities at 900-1100 °C in air provides a convenient one-pot synthesis route for 1: 2 B-site ordered double perovskite oxides, Ba3MM′ 2O9, that find application in microwave telecommunications.

AB - Solid state reaction of Li2CO3, MC2O 4·2H2O (M = Mg, Ni, Zn), M′2O 5 (M′ = Nb, Ta) and BaCl2 in stoichiometric quantities at 900-1100 °C in air provides a convenient one-pot synthesis route for 1: 2 B-site ordered double perovskite oxides, Ba3MM′ 2O9, that find application in microwave telecommunications.

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U2 - 10.1039/b616238j

DO - 10.1039/b616238j

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SN - 0959-9428

VL - 17

SP - 1589

EP - 1592

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 16

ER -

A novel one-pot metathesis route for the synthesis of double perovskites, Ba₃MM′₂O₉ (M = Mg, Ni, Zn; M′ = Nb, Ta) with 1: 2 ordering of M and M′ atoms

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